MEC&F Expert Engineers : 08/21/16

Sunday, August 21, 2016

5 injured after truck carrying five people was hit by another vehicle, causing the truck to rollover in Fayetteville, NC







It happened on Raeford Road (WTVD)

Sunday, August 21, 2016 08:11AM
FAYETTEVILLE (WTVD) -- Five people were hurt early Sunday morning in a crash in Fayetteville.

It happened after 5 a.m. on Raeford Road, police told our crew on the scene.

Officials told ABC11 a white Chevrolet truck carrying all five people was hit by another vehicle, causing the truck to rollover.

Police also told our crew an eyewitness was traveling behind the vehicle that hit the Chevy truck. According to that person, both vehicles were traveling inbound on Raeford Road, with the Chevy on the inside lane. The witness stated the truck attempted to make a turn into the Kangaroo convenience store, crossing the outside lane and into the path of the other vehicle.

The vehicle attempted to stop before hitting the truck, the witness told police. That vehicle reportedly slammed into the truck, and the Chevy rolled over several times. Officers have not confirmed the witness's story.

All five people injured in the crash were taken to Cape Fear Valley Medical Center for evaluation. Their conditions have not been released.

Police are still working to determine more details surrounding the crash. No charges have been filed.

Jaciel Espino-Montes, 22, of Goldsboro is facing charges including DWI after a crash killed 3 people, injured 3 others






Jaciel Espino, 22, faces charges including DWI (image courtesy Raleigh-Wake CCBI)

Updated 1 hr 17 mins ago
RALEIGH (WTVD) -- A driver is facing charges including DWI after a crash Sunday morning left 3 people dead. 3 other people in the car were injured.

Raleigh police responded to a single-vehicle wreck around 2:30 a.m. near the intersection of Highwoods Boulevard and Poplarwood Court.

Jaciel Espino-Montes, 22, of Goldsboro was charged with 3 counts of aggravated felony death by motor vehicle, 3 counts of aggravated serious injury by motor vehicle and driving while impaired.

According to the wreck report, the car went off to road and the driver overcorrected. The car then hit a light pole, a street sign, and a tree and flipped over. Two passengers were ejected.

There were 7 people in the vehicle, including the driver, according to the wreck report. Police said one person was sitting in the lap of someone in the backseat of the vehicle. Not everyone was wearing a seatbelt, authorities said.

Nelson Darinel Velazquez of Dudley, Tomas Rivera Jr. of Newton Grove, and Pau Bautista of Benson were all killed in the crash, according to the wreck report.

Police are still investigating.

2 people were swept off a breakwall due to high wind and waves in Frankfort, Michigan




Coast Guard urges public to heed weather warnings
Aug 21st, 2016 

MILWAUKEE, Wisc. – Following an incident in Frankfort, Mich., Sunday morning, the Coast Guard is urging the public to stay off breakwalls, jetties and low piers as hazardous weather passes through the area.

A crew from Coast Guard Station Frankfort responded when two people were swept off a breakwall due to high wind and waves just before 9 a.m. Sunday.

Benzie County sheriff’s initially reported the incident to the Coast Guard. Weather conditions at the time, waves up to 10 feet and winds up to 30 knots, exceeded operating parameters for Coast Guard boat crews, so a helicopter from Coast Guard Air Facility Muskegon was diverted and a crew from Coast Guard Station Frankfort drove a government vehicle to the breakwall.

Once there, the Frankfort crew discovered that one person was able to self-rescue then threw a life ring to the second person and pulled him to safety.

Weather in eastern Lake Michigan is forecast to remain hazardous throughout the day, making for dangerous conditions on breakwalls, jetties and low piers.

The National Weather Service forecast calls for waves up to 10 feet Sunday morning, decreasing to 7 feet Sunday afternoon and wind up to 30 knots Sunday morning, decreasing to 20 knots by Sunday afternoon.

“Those who wish to observe the high waves on Lake Michigan should do so from a safe location,” said Cmdr. Leanne Lusk, response department head at Sector Lake Michigan. “People who choose to ignore Coast Guard warnings put themselves and first responders in unnecessary danger.”

This comes just one month after two men lost their lives after being swept off a pier head in Sheboygan, Wisconsin, during a weather event July 17, 2016, when the Coast Guard received notice that 10 people had been swept into Lake Michigan by high waves in Wisconsin and Michigan in less than a two-hour period.

Taxi cab, another car crash outside bodega on Upper West Side in Manhattan








Eyewitness News
Sunday, August 21, 2016 08:23AM
UPPER WEST SIDE, Manhattan (WABC) -- A taxi cab and another car crashed on the Upper West Side early Sunday morning.

The taxi appears to have jumped a curb near a bodega, leaving the store's flower display in shambles.

It happened near West 74th Street and Amsterdam Avenue.

No pedestrians were injured.

It is not yet clear what caused the accident, or whether anyone inside the cars were hurt.

Three people dead, several injured after a high-speed head-on collision on the westbound Long Island Expressway near Shirley




3 dead, multiple injuries in accident on Long Island Expressway in Shirley



 
Updated 1 hr 19 mins ago
SHIRLEY, Long Island (WABC) -- Three people are dead and a number of others injured after a crash on the westbound Long Island Expressway.

The multi-car accident happened at about 9:35 a.m. Sunday near Exit 68 in Shirley.

Police say a speeding gray Subaru Outback was traveling eastbound on the LIE when the vehicle crossed over the grassy median, went airborne and struck two vehicles, a BMW and Honda that were traveling westbound.

The Subaru had five people inside. There were four people in the BMW and two in the Honda. Three people were pronounced dead at the scene, including the driver of the Subaru. There were two children who were injured, one critically.

Those involved were taken to local hospitals with minor to serious injuries.

The westbound LIE is closed to motorists at Exit 69 and the eastbound roadway is closed at exit 68.

The roadway is expected to be closed until at least 5 p.m. 


Detectives are investigating reports the dead driver of the Subaru was traveling at a high rate of speed.  He will not do this again.

YIELD TO THE FIRE TRUCK: FIREFIGHTERS INJURED AFTER KY LADDER AND HARROD CONCRETE TRUCK COLLIDE WHILE RESPONDING



KY LADDER AND CONCRETE TRUCK COLLIDE WHILE RESPONDING

August 20, 2016


Two firefighters were injured Friday afternoon when a Franklin County Fire Department ladder truck collided with a Harrod Concrete truck on Versailles Road.

The fire truck was responding to a call when the crash occurred, according to the Franklin County Sheriff’s Office.

The firefighters’ injuries were minor and the driver of the concrete truck was not injured, Sheriff Pat Melton said.

The fire truck and the concrete truck collided at the intersection of Versailles Road and Chenault Road.

As the fire department’s ladder truck was pulling out of Chenault Road with lights and sirens activated, a tractor trailer was in the slow lane on Versailles Road, Melton said. The tractor trailer prevented the driver of the fire truck and the driver of the concrete truck, which was in the passing lane of Versailles Road, from seeing each other.

The sheriff’s office is handling the investigation of the crash, but at this time no charges are anticipated, Melton said.

The intersection was re-opened by 6 p.m. Thursday.

“We’re just thankful that everybody is okay,” Melton said. “It could have been much worse. We’re just blessed that it was as minor as it was.”

Replacements will likely be called in to cover the firefighters that were injured for the rest of their shift, Melton said. The city of Frankfort is planning to lend the county a reserve ladder truck until damaged vehicle can be repaired.


Two many crashes occur between the responding fire trucks or responding firefighters and other vehicles.  So, please pay attention and yield to the fire truck or other EMS vehicles.








Alabama has the fourth-highest concentration of the dangerous PFAS chemicals in its water supply behind California, New Jersey and North Carolina.


Water study: Alabama has 4th highest level of PFAS contaminants
Andrew J. Yawn, Montgomery Advertiser 1:17 p.m. CDT August 20, 2016



(Photo: naumoid, Getty Images/iStockphoto)


A few months after a water advisory was issued for north Alabama due to high levels of PFASs (per- and polyfluoroalkyl substances), a Harvard University study has found that Alabama has the fourth-highest concentration of the chemicals in its water supply behind California, New Jersey and North Carolina.

PFASs are chemicals that repel water and are resistant to fire and oil. Because of these properties, PFASs have been used in household cleaners, fire fighting foams and Teflon cookware.

However, the scientific community is beginning to connect ingestion of PFASs to health issues which is why those shopping for a new non-stick frying pan will most likely see many touting the “PFOA-free” label in reference to perfluorooactanoic acid, a type of PFAS also found in some Alabama water supplies.

PFAS have now been linked to birth defects, cancer, obesity and immune system suppression, and the Harvard-led study found PFASs in the drinking water supplies of 16.5 million Americans.





Water supplies where PFASs were detected. (Photo: Environmental Science and Technology Letters)

Drinking water from 13 states accounted for 75 percent of the detections with Alabama having the fourth-highest amount of those 13.

The Alabama Department of Public Health and the Environmental Protection Agency issued a water advisory on May 19 after PFASs were found in eight north Alabama water systems.




"For the last three years, the levels of PFOS, PFOA and emerging contaminants in surface water have been monitored in all drinking water systems serving more than 10,000 people and in selected systems serving fewer people. ADPH will continue to review all studies and recommendations related to ingestion of these chemicals through public water supplies. ADEM is working with the named water systems to collect additional monitoring data where appropriate and to identify methods to reduce the water concentration of PFCs to a level below the final health advisory recommendation," reads the ADPH statement.

The north Alabama contamination has been linked to the 3M plant on the Tennessee River. Not only was 3M pinpointed as a source of PFAS contamination by the Harvard study due to its use of the chemicals in the manufacture of non-stick goods, but the company has also been named a defendant in a federal lawsuit filed by non-profit Tennessee Riverkeeper.


The red areas are water supplies with PFASs and the purple icons indicate manufacturing plants in the area. (Photo: Environmental Science and Technology Letters)

Chemical plant BASF in McIntosh, Ala., was also identified as an origin point for PFASs by the study. Water supplies around military fire training areas, airports and wastewater treatment plants were also found to contain PFASs with public water systems near manufacturing sites having an 81 percent higher chance of being contaminated by PFASs. Military sites increased risk by 35 percent, according to the study.




With at least 100,000 people in Alabama affected by the presence of PFAS-contaminated water, many are looking for a way to filter out the chemicals.

One of the eight Alabama water systems named by the EPA, the West Morgan-East Lawrence Water Authority, has a plan in place to put in a $4 million temporary filter until the permanent filter -- estimated to cost upwards of $30 million -- can be completed in 2019, according to several media reports.

When asked for comment, the EPA would only say that the study will be reviewed by the organization.

The EPA lowered the minimum reporting level of PFASs to 70 parts per trillion this year. After this study, regulation and cleanup of PFASs may get more stringent.


===================




Drinking water systems serving at least six million Americans have shown levels of C8 and other similar chemicals higher than a health advisory issued earlier this year by the U.S. Environmental Protection Agency, according to a new study published Tuesday by researchers from Harvard University and several other institutions and groups.

The study, though, cautions that another 44.5 million Americans rely on private wells that generally have not been sampled for these chemicals and another 52 million residents are served by small drinking water systems that are rarely sampled. And, the study further warns, studies continue to strongly suggest that exposure to these chemicals can make people sick, even at or below the concentration recommended as acceptable under the EPA health advisory.

“The EPA advisory limit ... is much too high to protect us against toxic effects on the immune system,” said study co-author Dr. Philippe Grandjean of the Harvard School of Public Health. “And the available water data only reveals the tip of the iceberg of contaminated drinking water.”

The study, published in the peer-review journal Environmental Science and Technology Letters, comes amid growing new attention for the potential threats from C8 and similar chemicals in the months following their discovery in water systems in New York and Vermont — a development that has driven political and media focus on the issue as residents near a DuPont Co. plant in Wood County, West Virginia, have waited for years for EPA to publish its new guidance.

The mid-Ohio Valley region around Parkersburg has for years been at the center of a simmering controversy over C8 pollution that has in recent months exploded into a larger national issue, with more intense media coverage, growing concerns in a variety of communities, and verdicts against DuPont in the first of thousands of pending personal injury cases to go to trial in a federal court in Ohio.

C8, which is also known as perfluorooctanoate acid, or PFOA, was made and used at DuPont’s Washington Works plant south of Parkersburg as a processing agent to make Teflon and other nonstick products, oil-resistant paper packaging and stain-resistant textiles.

DuPont and other companies have agreed on a voluntary phase-out of the chemical, but researchers noted in this week’s study that declines in production in the U.S. and Europe have been offset by increases in developing regions such as Asia. Scientists have also been increasingly concerned about chemical contamination of consumer products, and the new study provides important details about the potential threats from waste disposal practices and varying uses of the substances.

The study used computer mapping techniques to try to pinpoint the locations of contaminated drinking water supplies relative to potential sources of C8 contamination. Researchers said that they were hampered by the fact that regulators keep exact locations of drinking water intakes confidential, citing concerns about potential terrorist attacks. Instead of looking specifically at intake locations, the study focused on broader areas around those intakes, a move that may have missed impacts on groundwater, where contaminated plumes could be much smaller.

Researchers found that higher levels of chemicals were found in water supplies that were located closer to industrial sites, or to military bases or airports where firefighting foams containing some of the chemicals could have been used in emergeny drills. They also found higher levels in water supplies located near wastewater treatment facilities, which are generally not capable of removing the contamination as part of routine treatment.

Co-authors of the study included scientists from the University of California at Berkeley, the University of Rhode Island, the Colorado School of Mines, the Silent Spring Institute, the Green Science Policy Institute, the Environmental Working Group and EPA.

A second study that was also published Tuesday in the journal Environmental Health Perspectives added to previous evidence about immune system impacts of these chemicals, connecting early life exposure to reduced immune function.

Other recently published papers connected elevated exposure levels in women to shorter duration of breastfeeding, found higher levels of the chemicals in the blood of California women whose drinking water was contaminated, and found lower levels of growth and sex hormones in childen exposed to the chemicals


Study: At least 6 million at risk from PFOA chemical family


Ken Ward Jr. , Staff Writer
August 9, 2016
==================


























Michael Reaves, The Denver Post A water tower overlooks the community of Security in the foreground of Pike’s Peak on June 8, 2016. A invisible toxic chemical has been discovered in the drinking water that affects 70,000 people in the communities south of Colorado Springs.

By The Associated Press 

 UPDATED: August 18, 2016 at 3:34 pm



By JENNIFER McDERMOTT, Associated Press

The U.S. Air Force is changing the foam it uses to fight fires because of concerns the substance has contaminated groundwater and spread to drinking water at some military sites.

The Air Force said it awarded a $6.2 million contract on Monday to replace the firefighting foam with an “environmentally responsible foam” to reduce the risk of possible contamination of soil and groundwater.

The current foam is used where potentially catastrophic fuel fires can occur, such as in a plane crash, because it can rapidly extinguish the flames. It contains perfluorooctane sulfonate and perfluorooctanoic acid, or PFOS and PFOA, which are both considered emerging contaminants by the U.S. Environmental Protection Agency and have been linked to cancer and other illnesses.


The EPA issued stricter guidelines for human exposure to these chemicals in May, after years of pressure from public health experts and advocacy groups. The agency said the new limits were prompted by recent scientific studies linking the chemicals to testicular and kidney cancers, as well as birth defects and liver damage.

The chemicals have been detected in water at some current and former bases where the military has conducted fire or crash training. In Colorado, health officials said Wednesday that it’s highly likely that trace amounts of toxic chemicals found in three drinking water systems came from firefighting foam used at nearby Peterson Air Force Base, where firefighters used the foam in training exercises.

The new formulation does not have PFOS and contains little or no PFOA.

Mark Kinkade, spokesman for the Air Force Civil Engineer Center, said the Air Force has completed preliminary assessments at all of its sites and is now sampling groundwater and soil. He said the Air Force still has “a lot of work to do” but at the same time it’s working to protect human health and the environment by changing foams and taking other steps to ensure that foam is used safely.

Air Force fire chief James Podolske Jr. said the service must continue to use foam in its defense operations to protect people, weapon systems and infrastructure, but it will “do so in a more environmentally responsible way that also makes our operations safer for the public.”


The Air Force will no longer use the foam in training exercises, and the service plans to replace all foam in fire vehicles and at fire stations with the new formula by the end of this year. It also is retrofitting its aircraft rescue and firefighting vehicles with equipment that lets firefighters conduct vehicle operational checks and required annual foam tests without discharging the foam into the environment.

The Defense Department said earlier this year it’s examining hundreds of sites nationwide for potential contamination from the foam. It wasn’t immediately clear Thursday whether the Navy and Army are changing foams, too.

A Defense Department spokesman said the department is disposing of older foams, wherever possible, buying new foams that do not contain PFOS and investing in research to develop a foam that doesn’t contain the chemicals and can be certified to meet military standards.

PFOA has also been used in consumer products, such as nonstick pans, stain-resistant carpets and microwave popcorn bags, and has been found in the tap water of dozens of factory towns near industrial sites where it was manufactured.

============================




Michael Reaves, The Denver Post A water tower overlooks the community of Security in the foreground of Pike’s Peak on June 8, 2016. A invisible toxic chemical has been discovered in the drinking water that affects 70,000 people in the communities south of Colorado Springs.

By The Associated Press
PUBLISHED: August 17, 2016 at 4:56 pm | UPDATED: August 17, 2016 at 6:16 pm


 By Dan Elliott, The Associated Press

The military said Wednesday it has identified six places on an Air Force base in Colorado where firefighting foam containing toxic chemicals may have escaped into the environment and made its way into drinking water in two nearby communities.

Engineers who conducted the review recommended a follow-up investigation at Peterson Air Force Base, where the foam was used in firefighting drills and equipment tests. It contained perfluorinated compounds, or PFCs, which have been linked to prostate, kidney and testicular cancer, along with other illnesses.

The military is checking bases nationwide for possible releases of the foam into the environment.

It wasn’t immediately clear what the next phase of the investigation at Peterson would entail. The Air Force previously announced plans to drill monitoring wells and take soil samples to determine whether the chemicals were seeping into underground water from the base.

The PFCs were found in three water systems serving about 69,000 people in the city of Fountain and an unincorporated community called Security-Widefield. The chemicals have not been definitively traced to Peterson, but its proximity to the affected systems spurred the investigation.

The PFCs also were widely used in non-stick coatings on cookware and in other applications. The U.S. Environmental Protection Agency ordered water systems nationwide to test for the compounds between 2013 and 2015.

The Fountain, Security and Widefield districts found the chemicals at levels that exceed the EPA’s suggested limits. PFCs didn’t show up in any other districts.

Colorado health officials have said the communities have higher rates of kidney cancer than surrounding populations, but the evidence was not sufficient to definitively blame PFCs. They noted that the residents also have higher rates of obesity and smoking, which are linked to cancer.


The Air Force previously agreed to spend $4.3 million to install filters in the three systems to remove PFCs. Contractors were still working out the details, Peterson spokesman Steve Brady said.

The Security Water District has shifted almost entirely to surface water — from rivers and lakes — since the PFCs were found, Manager Roy Heald said Wednesday. Previously, about half the district’s water came from wells and half from surface water.

Heald expects the district to use surface water entirely soon, following modifications to the system.

The Fountain Water Department has not used wells since October and got through this summer’s peak demand period entirely on surface water, Utilities Director Curtis Mitchell said.

The director of the Widefield water system wasn’t immediately available to comment, his staff said.

=======================



DEADLY FOAM: the National Fire Laboratory is the source of perfluoroalkylated chemicals (PFAS) that contaminated the drinking water in Mississippi Mills, Ontario





Fire lab source of chemicals found in drinking water, NRC confirms
'This is the first time they've actually owned that piece of the mystery,' says mayor

By Ashley Burke, CBC News Posted: Jul 08, 2016 5:00 AM ET Last Updated: Jul 08, 2016 6:22 AM ET



Media toured the National Fire Lab in Mississippi Mills in February 2012. (CBC News)


Government officials have confirmed the National Fire Laboratory is the source of chemicals that contaminated the drinking water in Mississippi Mills, Ont.

Homeowners living near the facility found out in December 2015 that perfluoroalkylated substances, or PFAS, were discovered in their tap water. It's the same chemical often found in firefighting foams.
'They admitted they were essentially ground zero of the problem.' - Mississippi Mills Mayor Shaun McLaughlin

In an emailed statement to CBC News, the National Research Council confirmed Thursday that "ongoing environmental assessments have indicated that PFAS found in the nearby residential wells originated from the National Fire Laboratory site.

"Since identifying PFAS at the National Research Council's National Fire Laboratory, our focus has been on carrying out an effective and thorough environmental assessment and on the continued safeguarding of the health and safety of residents and employees," the statement said.

"They admitted they were essentially ground zero of the problem," said the municipality's mayor, Shaun McLaughlin. "This is the first time they've actually owned that piece of the mystery."

Back in 2013, the NRC knew contaminants were found in the groundwater from drill sites close to the facility.

Two years later, the government department started delivering bottled water to some neighbouring homes and paying for charcoal water filtration systems.


J.D. Heffern, his wife and three daughters learned their drinking water may be contaminated in December 2015. (Submitted Photo)
Residents pushing for answers

Ever since, residents in more than 70 homes in the community of Ramsay Meadows have been pushing for answers. The NRC says it's been carrying out environmental assessments.

"Results to date indicate low to no detection of PFAS in residential water..." said the NRC in a statement to CBC News. "According to Health Canada, there are no expected health impacts over a lifetime of exposure, if levels of PFAS in drinking water fall below the applicable Health Canada screening values."

A working group representing the Ramsay Meadows homeowners says they appreciate the NRC being honest about the results. The department's acting president, Maria Aubrey, met with two of the residents at the end of June.

"We are kind of taken aback a little bit," said chairperson J.D. Heffern. "They've come back and said here's the evidence. We've done testing to the west of the facility, we've done testing in various places and our conclusion is the National Fire Lab is in fact the source of the contaminants in a plume-like formation coming towards Ramsey Meadows."
Lingering concerns over health

Residents who live near the fire lab don't know how long they were exposed to the chemicals and what the impact could be.
'We don't know about the long-term effects.' - J.D. Heffern, chairperson of residents' working group

Scientific information is limited on PFAS, Health Canada says.

But in studies done on animals, "high levels of PFAS have been linked with negative health effects ... including liver damage and impacts on neurological development," the agency's fact sheet says.

In humans, short-term exposure to PFAS at levels slightly above the safety threshold isn't expected to have health effects, according to Health Canada, but the agency does not define what constitutes short- or long-term exposure.

"We don't know about the long-term effects," said Heffern.

A working group for Ramsay Meadows residents is meeting with Health Canada on July 12.


There is no public access to the NRC fire research lab in Mississippi Mills. (Stu Mills/CBC) 



==============================

Overview

Perfluoroalkyl substances (PFAS) are a large group of man-made chemicals that have been used in industry and consumer products worldwide since the 1950s.

 In the United States, making and using these chemicals in consumer products has greatly decreased during the last 10 years, but people can still be exposed  to PFAS because they are still present in the environment. 

Scientists have studied how PFAS affect animals’ health but are still trying to understand how exposure to PFAS affects human health. Over the last decade, interest in PFAS has been growing. ATSDR and our state health partners are investigating exposure to PFAS at a number of sites.

PFAS are heat, oil, grease, and water resistant.

The two best known groups of this family of chemicals are the perfluorocarboxylic acids (PFCAs), which include perfluorooctanoic acid (PFOA, sometimes called C8), and the perfluorosulfonates (PFSAs), which include perfluorooctane sulfonate (PFOS). 

PFCAs and PFSAs do not break down easily in the environment. They also bioaccumulate, or build up, in the blood and organs of exposed humans and animals and remain there for extended periods of time.
Some PFAS are precursors to PFCAs and PFSAs and can break down to those chemicals in the body or the environment.

The largest manufacturer of PFOS voluntarily stopped producing it in 2002. However, other countries still produce PFOS, and it can be imported into the United States in limited quantities. 

In 2006, EPA and major companies in the PFAS industry launched the 2010/2015 PFOA Stewardship Program. Companies participating in the program are working to stop producing PFOA and related chemicals by 2015. These companies include Arkema, Asahi, BASF Corporation (successor to Ciba), Clariant, Daikin, 3M/Dyneon, DuPont, and Solvay Solexis.


List of Perfluorosulfonates and Perfluorocarboxylic Acids and Their Abbreviations
Chemical
Abbreviation
Chemical Abstracts Service Registry Number (CAS No.)
Chemical Formula
Perfluorosulfonates (PFSAs)
Perfluorobutane sulfonate
PFBuS
375-73-5
C4HF9O3S
Perfluorodecane sulfonate
PFDS
335-77-3
C10HF21O3S
Perfluoroheptane sulfonate
PFHpS
375-92-8
C7HF15O3S
Perfluorohexane sulfonate
PFHxS
432-50-7
C6HF13O3S
Perfluorooctane sulfonate
PFOS
1763-23-1
C8HF17O3S
Perfluorooctanesulfonamide
PFOSA
754-91-6
C8H2F17NO2S

Perfluorocarboxylic acids (PFCAs)
Perfluorobutanoic acid
PFBA
375-22-4
C4HF7O2
Perfluorodecanoic acid
PFDA
335-76-2
C10HF19O2
Perfluorododecanoic acid
PFDoA
307-55-1
C12HF23O2
Perfluoroheptanoic acid
PFHpA
375-85-9
C7HF13O2
Perfluorohexanoic acid
PFHxA
307-24-4
C6HF11O2
Perfluorononanoic acid
PFNA
375-95-1
C9HF17O2
Perfluorooctanoic acid
PFOA
335-67-1
C 8HF15O2
Perfluoroundecanoic acid
PFUA
2058-94-8
C11HF21O2

 ======================================

 


Drinking water contamination with poly- and perfluoroalkyl substances (PFASs) poses risks to the developmental, immune, metabolic, and endocrine health of consumers. We present a spatial analysis of 2013–2015 national drinking water PFAS concentrations from the U.S. Environmental Protection Agency’s (US EPA) third Unregulated Contaminant Monitoring Rule (UCMR3) program. The number of industrial sites that manufacture or use these compounds, the number of military fire training areas, and the number of wastewater treatment plants are all significant predictors of PFAS detection frequencies and concentrations in public water supplies. Among samples with detectable PFAS levels, each additional military site within a watershed’s eight-digit hydrologic unit is associated with a 20% increase in PFHxS, a 10% increase in both PFHpA and PFOA, and a 35% increase in PFOS. The number of civilian airports with personnel trained in the use of aqueous film-forming foams is significantly associated with the detection of PFASs above the minimal reporting level. We find drinking water supplies for 6 million U.S. residents exceed US EPA’s lifetime health advisory (70 ng/L) for PFOS and PFOA. Lower analytical reporting limits and additional sampling of smaller utilities serving <10000 individuals and private wells would greatly assist in further identifying PFAS contamination sources.

Introduction


Poly- and perfluoroalkyl substances (PFASs) make up a large group of persistent anthropogenic chemicals used in industrial processes and commercial products over the past 60 years.(1) Widespread use and extreme resistance to degradation have resulted in the ubiquitous presence of these compounds in the environment. The 2011–2012 U.S. National Health and Nutrition Examination Survey reported detectable serum PFAS concentrations in virtually all individuals (97%).(2, 3) Human PFAS exposure has been linked to cancer, elevated cholesterol, obesity, immune suppression, and endocrine disruption.(4-6) Health concerns in the early 2000s prompted manufacturers in Europe and North America to phase out production of some long-chain PFASs.(7-10) Declines in production of these compounds have been offset by increases in developing regions such as Asia.(8) Limited available data suggest widespread exposure to replacement (short-chain) PFASs may also adversely affect human health.(11, 12)
Human PFAS exposure includes dietary sources, household dust, air, and drinking water.(13, 14) Exposure from drinking water is a serious concern because of the high aqueous solubility of many PFASs.(15, 16) Relatively low PFAS concentrations can lead to elevated exposures in the general population.(17) Elevated PFAS concentrations in U.S. drinking water have been reported in numerous regions,(15, 16, 18, 19) especially near industrial sites that produce or use them.(6, 16, 20) For example, perfluorooctanoic acid (PFOA) concentrations 190-fold higher than the lifetime health advisory (70 ng/L) recommended by the U.S. Environmental Protection Agency (US EPA)(21) were measured in drinking water near a fluorochemical facility in Washington, WV, where PFOA was used in fluoropolymer production.(18)
Many civilian airports and military fire training areas have been contaminated by PFASs contained in aqueous film-forming foams (AFFFs) that are widely used during firefighting training activities. Groundwater and surface waters surrounding these sites containing PFAS concentrations that are 3–4 orders of magnitude higher than the US EPA health advisory level for drinking water have been reported.(22, 23) Wastewater treatment plants (WWTPs) are another important PFAS source because these compounds are not removed by standard treatment methods(24) and labile precursors biodegrade, increasing concentrations in effluent relative to influent.(25, 26) Land application of approximately half of the biosolids generated by WWTPs may contribute to human exposure through subsequent contamination of water, food, livestock, and wildlife.(27)
Understanding nationwide PFAS exposures from drinking water is important for identifying potentially vulnerable populations. However, previous studies have mainly focused on individual point sources of PFAS contamination and site-specific drinking water exposures.(15, 16) Here we develop a statistical framework for investigating whether increased PFAS concentrations in drinking water are associated with the number of point sources within a watershed (represented by an eight-digit hydrologic unit code, hereafter abbreviated HUC). We used publicly available drinking water concentration data for six PFASs from the US EPA’s third Unregulated Contaminant Monitoring Rule (UCMR3), including perfluorobutanesulfonic acid (PFBS), perfluorohexanesulfonic acid (PFHxS), perfluoroheptanoic acid (PFHpA), PFOA, perfluorooctanesulfonic acid (PFOS), and perfluorononanoic acid (PFNA) (Table S1).(28) We discuss the utility of the UCMR3 database for identifying sources of PFASs to U.S. drinking water supplies, locations of vulnerable populations, and priorities for future monitoring.

Methods


Drinking Water Data
Our analysis included analytical results for six PFASs in 36149 drinking water samples from the US EPA’s UCMR3 program collected between January 2, 2013, and December 9, 2015.(28) Samples cover all 4064 public water supplies serving >10000 individuals. Data are also available for 800 public water supplies serving <10000 individuals, but this represents only a small fraction (0.5%) of the 144165 in this category. Minimum reporting levels (MRLs) for the six PFASs analyzed are listed in Table S1.
One limitation of the UCMR3 database is that national data on system intakes for public water supplies are classified,(29) making it difficult to place them within a specific hydrological network. We therefore extracted the zip codes for areas served and aggregated data within eight-digit HUCs(30) to capture the most detailed hydrologic information that exceeds the spatial resolution of PFAS data (zip code areas). We used the highest reported PFAS concentrations when multiple systems were located within a single zip code and/or when multiple zip code areas were located within the same HUC.
PFAS Point Sources
Our spatial analysis (Figure S1) included point source information for (a) 16 industrial sites listed in the US EPA’s 2010/2015 PFOA Stewardship Program (Table S2),(31) (b) 8572 WWTPs,(32) (c) 290 military fire training areas that contain 664 military fire training sites,(33) and (d) 533 civilian airports that are compliant with Title 14 Code of Federal Regulations, Part 139 for personnel trained in the use of AFFF (hereafter termed “AFFF-certified airports”).(34) PFASs produced and/or used vary across industrial sites, and not all compounds were associated with all sites. For example, a fluorochemical manufacturing facility in Decatur, AL, produced both PFOS and PFOA,(35) while only PFOA was used in the manufacturing process of another fluorochemical production facility in Parkersburg, WV.(36) We conducted a sensitivity analysis to examine the potential production misclassification bias by limiting industrial sites to include the ones that only produced or used each specific compound (Table S3). We used the Google Maps application program interface (API) to geocode coordinates based on addresses. Potentially important PFAS sources such as landfills, biosolids, and small industrial PFAS users could not be included in this analysis because comprehensive geospatial data are not available.
Spatial and Statistical Analysis
We used ArcMap 10.3.1 (ESRI) to explore statistical differences between the number of point sources in eight-digit HUCs with PFAS levels above and below the level of detection. We developed a multivariate spatial regression model for watersheds with detectable PFASs that adjusts for correlations and co-location among point sources. A natural log transformation was used to normalize the distribution of individual PFASs. PFNA and PFBS were excluded from the spatial regression analysis due to a low detection frequency (15 and 14 of 1601 watersheds, respectively). We used Moran’s I statistic to test for spatial dependence in the model residuals from an ordinary least-squares (OLS) regression and correct for spatial dependence in the final spatial regression model. Akaike Information Criterion(37) was used to compare the OLS and spatial regression models, where a lower value implies a better model fit. A series of cross-validation tests were also completed to assess the predictive capacity and stability of the final set of models. The OLS and spatial regression models were constructed using GeoDa 1.6 software,(38) and cross-validation was implemented in R version 3.1.3.

Results and Discussion


PFASs in U.S. Drinking Water
PFASs were detected at or above the MRLs in 194 of 4864 public water supplies, serving 16.5 million residents in 33 different states, three American territories (American Samoa, Northern Mariana Islands, and Guam), and the Salt River Pima-Maricopa Indian Community. Drinking water from 13 states accounted for 75% of detections, including, by order of frequency of detection, California, New Jersey, North Carolina, Alabama, Florida, Pennsylvania, Ohio, New York, Georgia, Minnesota, Arizona, Massachusetts, and Illinois (Figure 1). Detection frequencies for PFASs across the 4864 public water supplies were 2.2% for PFOA, 2.0% for PFOS, 1.7% for PFHpA, 1.1% for PFHxS, and <0.003% for others.
figure
Figure 1. Hydrologic unit codes (eight-digit HUCs) used as a proxy for watersheds with detectable PFOA and PFOS in drinking water measured in the US EPA’s UCMR3 program (2013–2015). Blank areas represent regions where no data are available.

Many detectable PFAS concentrations in the UCMR3 database are above chronic drinking water and water quality standards for other regions (i.e., surface water European Union, PFOS, <1 ng/L; drinking water Sweden, sum of seven PFASs, <90 ng/L; groundwater State of New Jersey, PFNA, <10 ng/L; drinking water State of Vermont, sum of PFOS and PFOA, <20 ng/L).(39-42) A recent analysis developed a benchmark dose for immunotoxicity in children and suggested a drinking water limit of approximately 1 ng/L for PFOS and PFOA.(26) Data from rodents that measured sensitive end points such as mammary gland development support a similar level.(26)
Six million people were served by 66 public water supplies that have at least one sample at or above the US EPA’s 2016 health advisory for PFOS and PFOA (70 ng/L individually or combined). Concentrations ranged as high as 349 ng/L for PFOA (Warminster, PA), 1800 ng/L for PFOS (Newark, DE), and 56 ng/L for PFNA (Woodbury, NJ).
The detection frequency in drinking water sourced from groundwater was more than twice that from surface water (Table S4). Long-chain PFASs(43) (PFHxS, PFOS, PFOA, and PFNA) were more frequently detected in groundwater, and short-chain compounds (PFHpA and PFBS) were detected more frequently in surface waters. This may be due to both the original mode of environmental release (as an aerosol, application to soil, and aqueous discharge) and the inverse relationship between PFAS mobility and chain length.(44) The MRLs (10–90 ng/L) in the UCMR3 database are up to 2 orders of magnitude higher than the limit of quantitation in most published studies,(45-49) and more than 10 times higher than the drinking water limit (1 ng/L) suggested by human and animal studies.(26, 50) Because PFASs are detectable in virtually all parts of the environment,(5, 7, 9, 13, 14, 20, 44, 51) we infer that the large fraction of samples below reporting limits (Table S4) is driven in part by high MRLs.
Sources Surrounding Locations with Detectable PFASs

Our analysis indicates point sources are significantly more abundant in HUCs with detectable PFASs [two-sided t test, p < 0.05 (Table 1 and Figure S2)]. This includes drinking water samples from 1601 of the 2158 total U.S. HUCs. For example, HUCs with detectable PFOA levels (8% of the total) have more industrial sites, military fire training areas, AFFF-certified airports, and WWTPs than those with concentrations below detection. These trends can be observed across all PFASs. Similarly, HUCs with point sources have higher detection frequencies for PFASs (Table S5). 
For example, the presence of a military fire training area within a HUC increases the frequency of detection of at least one PFAS from 10.4% to 28.2%. One caveat is that imprecise information about public water supply intakes can cause misclassification bias. Systems that draw water upstream from point sources, such as Minneapolis and St. Paul in Minnesota, may not actually be affected as indicated by the aggregated spatial analysis.
Table 1. Mean Abundance of Point Sources within Eight-Digit Hydrologic Unit Codes (HUCs) with Drinking Water PFAS Concentrations above and below the Method Reporting Limit in the UCMR3 Program
mean abundancea within eight-digit hydrologic unit codes
compoundmajor industrial sitesbmilitary fire training areasAFFF-certified airportsWWTPsc
PFBS
<90 ng/L (n = 1587)0.010.150.294.9
>90 ng/L (n = 14)0.210.710.5014.6
p-valued0.2060.1050.1480.069
PFHxS
<30 ng/L (n = 1507)0.010.130.274.8
>30 ng/L (n = 94)0.060.600.638.8
p-value0.056<0.001<0.001<0.001
PFHpA
<10 ng/L (n = 1509)0.010.130.264.7
>10 ng/L (n = 92)0.090.570.679.7
p-value0.016<0.001<0.001<0.001
PFOA
<20 ng/L (n = 1473)0.010.130.264.6
>20 ng/L (n = 128)0.050.520.569.5
p-value0.038<0.001<0.001<0.001
PFOS
<40 ng/L (n = 1487)0.010.130.264.7
>40 ng/L (n = 114)0.050.540.578.9
p-value0.064<0.001<0.001<0.001
PFNA
<20 ng/L (n = 1586)0.010.150.284.9
>20 ng/L (n = 15)0.131.131.1320.1
p-value0.3660.0140.0080.007
a
The mean abundance is calculated as the mean number of point sources within HUCs with PFASs above or below the level of detection.
b
Only the major industrial sites participating in the US EPA’s 2010/2015 PFOA Stewardship Program were included.
c
Wastewater treatment plant.
d
Two-sample t-test p-values.

Results of the Spatial Regression Model

Spatial regression modeling explains 38–62% of the variance in drinking water concentrations for the four PFASs considered (Table 2). Each additional industrial site within a HUC is associated with an 81% increase in PFOA (p < 0.001), which is the strongest statistical association across compounds and point sources. Increasing PFOS concentrations are positively associated with the number of industrial sites, but this relationship is not statistically significant (p = 0.124). The small number of sites that have manufactured or used PFOS likely accounts for the lack of a statistically significant relationship.
Table 2. Spatial Regression Models for Drinking Water PFAS Concentrations as a Function of the Abundance of Point Sources
compoundmajor industrial sitesaMFTAsbAFFF-certified airportsWWTPscλdR2
PFHxS
coefficiente24%20%–13%1%94%0.62
p-valuef0.2490.0020.0730.045<0.001
PFHpA
coefficient10%10%–2%0.5%72%0.40
p-value0.5690.1550.7610.436<0.001
PFOA
coefficient81%10%–6%2%52%0.38
p-value<0.0010.1110.3530.006<0.001
PFOS
coefficient46%35%–6%2%79%0.46
p-value0.124<0.0010.5120.007<0.001
a
Only the major industrial sites participating in US EPA’s 2010/2015 PFOA Stewardship Program were included.
b
MFTA = military fire training area.
c
WWTP = wastewater treatment plant.
d
Coefficient for the spatial error term characterizing spatial influence.
e
Results have been transformed to reflect expected changes in drinking water concentrations per increase in the abundance of different sources. Positive coefficients in the results indicate increasing concentrations with an increasing abundance of point sources within the same hydrologic unit.
f
p-values for the spatial error regression model. The spatial error term is used to incorporate spatial autocorrelation structures into a linear regression model.
The number of military fire training areas within each HUC is positively associated with increasing levels of all PFOS, PFOA, PFHxS, and PFHpA, and is statistically significant for PFHxS (p = 0.045) and PFOS (p = 0.007). Each additional military fire training area within the same HUC is associated with a 20% increase in PFHxS (p = 0.002), a 10% increase in PFHpA (p = 0.155), a 10% increase in PFOA (p = 0.111), and a 35% increase in PFOS (p < 0.001). AFFFs typically contain relatively high concentrations of PFOS and PFHxS and their polyfluorinated precursors compared to the concentrations of other perfluorinated carboxylates,(23, 52-54) which is consistent with these statistical results.
We find a small but significant increase in PFOS and PFOA (2%; p < 0.01) with each additional WWTP within the same HUC. This is consistent with the greater abundance but smaller quantities of PFASs released by WWTPs.(55) Similarly, results of Valsecchi et al.(51) show PFAS releases from WWTPs are important but less significant than those from fluorochemical manufacturing facilities in Italy. The number of WWTPs may also be a proxy for other population-driven PFAS sources.
The number of AFFF-certified airports is not significantly associated with PFAS concentrations in the current data set. This may reflect misclassification bias because the certification used to identify airports indicates eligibility but not actual use of AFFF. The UCMR3 database contains limited data for smaller drinking water systems where localized reports of contamination from airports have been most abundant.(22, 56)
Current Data Limitations and Future Monitoring Efforts

The UCMR3 database has several limitations that restrict its predictive power for identifying U.S. drinking water supplies likely to contain elevated levels of PFASs. Classification of geospatial data on intakes for public water supplies limits the spatial resolution of the current data set and associated statistical models to a radius of 50 km (median radius of watersheds).(57, 58) Many of the impacted drinking water systems are groundwater systems, and contaminated groundwater plumes are often much smaller than 50 km.(23, 53, 59)
Geospatial data are lacking for many potentially important PFAS point sources such as a wide range of industries, landfills, biosolids application, and other AFFF-impacted sites where relatively smaller volumes of AFFF were released.(27, 54, 60-67) Data on PFAS releases from smaller industrial facilities (e.g., plastics, textiles, paper, and lubricants) are usually withheld as confidential business information, and little information about airborne emissions is available for characterizing the importance of atmospheric releases and potential long-range transport. For example, biosolids application resulted in one of the largest PFAS drinking water contamination events in Europe(68) but could not be included in this analysis because U.S. use data are not available on a national scale.
Sources not included in our spatial analysis are represented by the highly significant lambda (λ) coefficients (Table 2). Areas with high model residuals (greater than 1.5 standard deviation) mean that current information about sources cannot fully explain the high observed PFAS concentrations. The map of model residuals (Figure S3) can thus be used to guide high-priority sampling regions in future work.
We found a statistically greater abundance of point sources in watersheds with detectable PFASs, including AFFF-certified airports. However, multivariate spatial regression models did not show a significant association between AFFF-certified airports and concentrations of PFASs in nearby drinking water. Other studies have reported elevated PFAS concentrations in groundwater wells adjacent to AFFF-certified airports.(22) Small drinking water systems and private wells may be disproportionately affected by PFASs originating from AFFF use at civilian airports, but representative data for these small drinking water systems are not included in the UCMR3 program.(69)
Approximately 44.5 million U.S. individuals rely on private drinking water wells,(70) and 52 million individuals rely on smaller public water supplies (<10000 served). The UCMR3 program includes 0.5% testing incidence for smaller public water supplies(71) and no testing of private wells, meaning that information about drinking water PFAS exposures is therefore lacking for almost one-third of the U.S. population.
Supporting Information
The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.estlett.6b00260.
  • Additional tables and figures (PDF)
The authors declare no competing financial interest.

Acknowledgment


We acknowledge financial support for research at Harvard from the Smith Family Foundation and a private donor. We thank Marcia Castro (Harvard) for her feedback on an earlier version of the manuscript and Jahred Liddie (Harvard) for his assistance with the sensitivity analysis. T.A.B. was supported by the U.S. National Institute for Environmental Health Sciences (NIEHS) Superfund Research Program (Grant P42 ES004705) and the Superfund Research Center at the University of California, Berkeley. The views expressed in this article are those of the authors and do not necessarily represent the views or policies of the U.S. Environmental Protection Agency.

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