MEC&F Expert Engineers

Friday, November 28, 2014

CSB RELEASES BOARD APPROVED REGULATORY REPORT ON CHEVRON REFINERY FIRE - PROPOSES A MORE RIGOROUS REFINERY INDUSTRY REGULATORY SYSTEM IN CALIFORNIA



CSB Releases Board Approved Regulatory Report on Chevron Refinery Fire - Proposes a More Rigorous Refinery Industry Regulatory System in California

Washington, DC. November 10, 2014– In the final Regulatory Report unanimously approved by the CSB Board and released to the public today, the U.S. Chemical Safety Board (CSB) proposes recommendations for substantial changes to the way refineries are regulated in California.  Entitled “Regulatory Report: Chevron Richmond Refinery Pipe Rupture and Fire,” the CSB report calls on California to enhance its process safety management (PSM) regulations for petroleum refineries to ensure a more robust and adaptive regulatory regime.  
The Regulatory Report is the second part of three in the CSB’s investigation of the August 2012 process fire in the crude unit at the Chevron refinery in Richmond, California. That fire endangered 19 workers and sent more than 15,000 residents to the hospital for medical attention.


CSB Chairperson Dr. Rafael Moure-Eraso said, “The CSB will be holding a public meeting in mid December to release the third part of its investigation. The goal of the CSB’s work is to protect worker and public safety in California I have great confidence that California will embrace the recommendations in our Regulatory Report.”

The CSB’s investigation of the incident found that Chevron repeatedly failed over a ten-year period to apply inherently safer design principles and upgrade piping in its crude oil processing unit, which was extremely corroded and ultimately ruptured on August 6, 2012.  The CSB’s first report on the incident identified missed opportunities on the part of Chevron to apply inherently safer piping design through the use of more corrosion-resistant metal alloys. The first report also found a failure by Chevron to identify and evaluate damage mechanism hazards, which if acted upon, would likely have identified the possibility of a catastrophic sulfidation corrosion-related piping failure. There are currently no federal or state regulatory requirements to apply these important preventative measures. The investigation team concluded that enhanced regulatory oversight with greater worker involvement and public participation are needed to improve petroleum refinery safety.



Following the Chevron Richmond refinery incident, the state of California has worked to revise and strengthen its PSM requirements.  On September 9, 2014, the State of California Department of Industrial Relations, Division of Occupational Safety and Health (Cal/OSHA) released its Draft Process Safety Management for Refineries Regulation.  The draft regulation includes a number of more rigorous requirements.  .   The draft regulation incorporates a risk-reduction goal of “the greatest extent feasible” for process hazard analyses and proposes significant new requirements such as performing damage mechanism reviews and hierarchy of controls analysis.  Chairperson Moure-Eraso added, “California’s draft regulations address numerous issues raised in the CSB regulatory report, and the CSB will be monitoring the California rulemaking process closely to see if those  provisions remain in the final rule.”

At a January 2014 public meeting in Richmond, CA the board approved a motion to allow for additional study of this incident. Since that time CSB staff and board members have traveled to the UK to fully study regulatory regimes of onshore and offshore facilities in the UK– amongst a number of issues staff examined workforce participation, continual improvement and transparency issues as the currently exist in the UK.  The CSB staff outlined these actions in a white paper available at www.csb.gov.


Investigator Amanda Johnson said, “The CSB’s regulatory report concludes that under the existing U.S. and California regulatory systems, there is no requirement to reduce risks to a specific target, such as, for example, to as low as reasonably practicable, or ALARP, – similar principles have been adopted  in Europe and Australia in the refinery and chemical sectors, as well as the nuclear and space sectors in the U.S.” Such a target would also require adaptability and continuous improvement which is vital in responding to newly discovered hazards and lessons from chemicals incidents.
Dr. Rafael Moure-Eraso said, “The current regulatory system for process safety is largely reactive, at both the state and federal level; companies have a default right to operate, and are subject to penalties when accidents occur or their activities otherwise draw negative attention from regulators.  In the case of the Chevron refinery fire, the reactive system of regulation simply did not work to prevent what was ultimately a preventable accident.”


The regulatory report details how attributes of a more robust and adaptive process safety management approach would greatly enhance existing state and federal process safety regulations.  Such attributes include a more comprehensive process hazard analysis; documented use of inherently safer systems analysis and the hierarchy of controls to the greatest extent feasible with the goal of continuous risk reduction to a specified risk target; analysis of the effectiveness of safeguards intended to control hazards; the effective use of process safety indicators that drive performance; and more thorough inspections and audits by a technically qualified regulator.  The CSB notes that these enhancements would provide the adaptability necessary to keep current with improving standards and advancing technology, without requiring lengthy and often unproductive rulemaking on the part of the regulator. 
Effective implementation of this system requires strong workforce involvement, proactive inspections and enforcement by a well-resourced regulator, as well as incorporation of best practice performance standard requirements. Don Holmstrom, director of the CSB’s Western Regional Office noted that the Chevron report recommends significant improvements to empower workers and their representatives. “The report recommends that the regulator recognize worker safety representatives who have the right to participate in improvements to process safety and if necessary have the legal authority to stop unsafe work—the Chevron incident showed these reforms are sorely needed.”     

     
 

Chairperson Moure-Eraso said, “Workers, the public and the industry itself would benefit from an adaptable, robust and effective regulatory approach. The recent bipartisan law passed last month by the California legislator to provide regulators with detailed information concerning extensive maintenance overhauls and repair operations at refineries within the state is certainly a step in the right direction.”        The CSB is an independent federal agency charged with investigating serious chemical accidents. The agency's board members are appointed by the president and confirmed by the Senate. CSB investigations look into all aspects of chemical accidents, including physical causes such as equipment failure as well as inadequacies in regulations, industry standards, and safety management systems.
The Board does not issue citations or fines but does make safety recommendations to plants, industry organizations, labor groups, and regulatory agencies such as OSHA and EPA. Visit our website, www.csb.gov.
For more information, contact Communications Manager Hillary Cohen, cell 202-446-8094 or Sandy Gilmour, Public Affairs, cell 202-251-5496.



USA, CA, RICHMOND, NOVEMBER 13 2014. CSB RELEASES FINAL REPORT ON CHEVRON RICHMOND REFINERY FIRE
The US Chemical Safety Board (CSB) has issued the final regulatory report on its investigation of the August 2012 pipe rupture and ensuing fire at Chevron Corp.’s 257,000-b/d Richmond, Calif., refinery, in which the agency reinforced its call for a more-rigorous approach to safety management at US refineries. CSB released the report, which received unanimous approval by agency board members, on Nov. 10. The second of three parts in CSB’s investigation of the Aug. 6, 2012, process fire and vapor release at the Richmond refinery’s crude unit (OGJ Online, Aug. 7, 2012), this latest report reiterates CSB’s previous recommendation for California and US refiners to implement a safety case regulatory regime similar to that already adopted by refiners in Norway, the UK, and Australia (OGJ Online, Dec. 17, 2013). The shift to a safety-case regime would represent a fundamental change to current US practices by shifting the responsibility for continuous reductions in major accident risks from regulators to the company by requiring companies to demonstrate to refinery industry regulators—through a written “safety case report”—how major hazards are to be controlled and risks reduced to as low as reasonably practicable. Specifically, the report describes attributes of the safety case regulatory scheme that would help to transform the US’s currently “reactive” PSM system into a more proactive one, according to CSB.
Worker, Safety Requirements
·           In contrast to the PSM system used by US federal and state regulators today, the safety-case regulatory regime would improve worker and public safety by requiring:
·           More comprehensive process hazard analyses.
·           Documented use of inherently safer systems analysis and the hierarchy of controls to the greatest extent feasible, with the goal of continuous risk reduction to a specified risk target.
·           Analyses of the effectiveness of safeguards intended to control hazards.
·           Effective use of process safety indicators that drive performance.
·           More thorough inspections and audits by a technically qualified regulator.

These enhancements would provide US regulators the adaptability necessary to keep current with improving standards and advancing technology, without requiring the regulatory bodies to engage in the process of lengthy and often unproductive rulemaking, CSB said. The agency also lauded the California Division of Occupational Safety and Health’s (Cal/OSHA) recent move to revise and strengthen PSM requirements for state refiners with the September release of its Draft Process Safety Management for Refineries Regulation (PSMRR). In addition to incorporating a risk-reduction goal of “the greatest extent feasible” for process hazard analyses, Cal/OSHA’s draft PSMRR proposes new requirements such as performing damage mechanism reviews and hierarchy of controls analyses. “California’s draft regulations address numerous issues raised in the CSB regulatory report, and the CSB will be monitoring the California rulemaking process closely to see if those provisions remain in the final rule,” said CSB Chair Rafael Moure-Eraso. CSB said it will release the third part of its investigation into the Richmond refinery fire at a public meeting in mid-December. In its first report on the incident, CSB found that Chevron repeatedly failed over a 10-year period at the Richmond refinery to apply inherently safer design principles and upgrade piping in the crude oil processing unit, which was extremely corroded and ultimately ruptured by the time of August 2012 incident (OGJ Online, Apr. 15, 2013). Had Chevron identified and evaluated damage mechanism hazards, the possibility of a catastrophic sulfidation corrosion-related piping failure likely would have been detected and prevented, according to CSB.



Metropolitan Engineering, Consulting & Forensics (MECF)
Providing Competent, Expert and Objective Investigative Engineering and Consulting Services
P.O. Box 520
Tenafly, NJ 07670-0520
Tel.: (973) 897-8162
Fax: (973) 810-0440
We are happy to announce the launch of our twitter account. Please make sure to follow us at @MetropForensics or @metroforensics

Metropolitan appreciates your business.
Feel free to recommend our services to your friends and colleagues.


THE FIRE AND EXPLOSION RISKS ASSOCIATED WITH ETHANOL PRODUCTION AND TRANSPORTATION



THE FIRE AND EXPLOSION RISKS ASSOCIATED WITH ETHANOL PRODUCTION AND TRANSPORTATION




In the last fifteen years, the production of ethanol has increased dramatically due to the demand for ethanol-blend fuels.  Current production (November 2014) in the United States is almost 15 billion gallons (14.932 billions).  On December 19, 2007, the Energy Independence and Security Act of 2007 was signed into law.  

This comprehensive energy legislation amended the Renewable Fuels Standard (RFS) signed into law in 2005, growing the RFS to 36 billion gallons in 2022.  There are 213 nameplate refineries, with additional refineries being proposed/expanded.  Most the ethanol refineries are located in the Midewest and upper Midwest.  Ethanol is produced by fermentation and distillation processes.  

The most common ethanol concentration leaving a biorefinery is denatured fuel ethanol which consists of 98% ethanol and 2% denaturing agent (rust inhibitor).  Natural gasoline is also mixed with the alcohol, prior to shipment.


 The yellow circles indicate refineries under construction.  The green circles are operational ethanol plants.

Denatured ethanol is largely shipped from production facilities by rail and is now the largest volume hazardous material shipped by rail. 
Large volumes of ethanol are commonly shipped by unit trains, up to 3.5 million gallons, and the larger barges can transport up to 2.5 million gallons.  In Massachusetts, two to three ethanol unit trains currently travel through the state per week, as well as an ethanol barge per week.  The number of trains and barges transporting denatured ethanol (95% - 98% ethanol) through the state are anticipated to increase in the future, especially if the use of higher ethanol blends becomes more prevalent. 

The high volume of ethanol transported and the differences in the chemical properties, and the fate and transport of ethanol as compared to standard gasoline, led to the need for additional consideration of spill response actions. In particular, this document considers the assessment and response actions for rail and barge spills of denatured ethanol. 



Ethanol is a flammable colorless liquid; a polar solvent that is completely miscible in water. It is heavier than air, and has a wider flammable range than gasoline, with a Lower Explosive Limit (LEL) to an Upper Explosive Limit (UEL) range of 3.3% to 19%. The flash point for pure ethanol is 55°F, and for denatured ethanol it is much lower (-5°F). 

Ethanol is still considered a flammable liquid in solutions as dilute as 20%, with a flash point of 97°F. At colder temperatures (below about 51°F), the vapor pressure of ethanol is outside the flammable range. Denatured ethanol is shipped with a flammable liquids placard and North American 1987 designation. 

Here is a partial list of some fires and explosions involving ethanol plants across the United States.  Due to the flammable and explosive nature of the process, these fires and explosions occur at some frequency.



 ETHANOL PLANT EXPLOSION OR FIRE
PLANT
LOCATION OF FIRE/EXPLOSION
DATE



Arkalon Energy LLC, Liberal, Kansas
A corn dryer caught fire and exploded.  The combustion chamber of the dryer exploded due to natural gas.
29-Jun-14
Green Plains Renewable Energy, Fergus Falls, MN
A hydraulic pump which controls the damper in the dryer building of the Green Plains Renewable Energy plant failed
13-Mar-14
Flint Hill Resources, Arthur, Iowa - Platinum Ethanol Plant, 2585 Quail Avenue, Arthur, IA
A distilled grains dryer exploded, damaging a unit of the building.
17-Jul-14
Badger State Ethanol Plant 820 W. 17th Street
P.O. Box 317 Monroe, WI 53566
small fire and explosion in silo
23-06-07
Ethanol of Florida, E 1705 Mann Rd , Bartow FL Polk - County
a tank containing alcohol exploded near the rear of an ethanol plant
24-04-09
Abengoa Bioenergía , 395 Bissell St. Madison, IL, 63060, USA
Men were working near a container in a maintenance shed when the container exploded.
11-04-11
Lincolnway Energy, 59511 West Lincoln Highway, Nevada, Iowa
Explosion at the ethanol plant.  A power surge caused a steam pipe to burst, burning the workers who were performing maintenance nearby
11-11-07
American AG Fuels, Defiance, Ohio
unknown reason for blast, but happened in loading area
04-01-08
Appomattox Bio Energy Plant, 701 S. 6th Avenue, Hopewell Virginia 23860
vapors back-up and the vapors were in a device that has a burner in it and so the vapors ignited
09-09-10
Chief Industries, 4225 E South St. • PO Box 488 • Hastings, NE 68901
the men opened the door of a grain grinder while doing maintenance and a small explosion occurred.
Mar. 6, 2009
Poet Ethanol Plant , 27716 462ND AVE. CHANCELLOR, SD 57015
issue with feed dryer. Worker were taking downt he dryer when a a small amount of dust ignited.
24-08-10
Pinal Energy, 38585 W Cowtown Rd Maricopa, AZ 85139
the explosion was possibly the result of corn by-product dust particles that were ignited by a heating system used in the ethanol-producing drying process.
09-10-09
Central Minnesota Ethanol Co-op in Little Falls, Minn.
the damage was contained to a biomass gasification system
03-10-07
Chippewa Valley Ethanol Co. 270 20th St. NW, Benson, MN 56215
A tank holding 40,000 gallons of corn mash, exploding with a "whoosh and a flash"
Oct. 22, 2003
A LyondellBasell US ethanol 625 East US Highway 36,
Tuscola, IL 61953
plant rocked by an explosion on Monday
22-03-10
Collingwood Ethanol plant
fire in silo
13-05-09
Amaizeingly Green L.P formerly Collingwood Ethanol
The company was convicted of a number of charges laid by
the MOE related to odour and noise issues.
2009
Tharaldson ethanol plant 3549 153rd Avenue SE Casselton, ND 58012
contained to a dust collection bin.
28-02-09
Constellation New Energy Inc
3201 West Calvert Street South Bend, IN 46613-1010
fire not clear
12/30/10
Bushmills Ethanol, Atwater, MN 56209
fire on conveyor belt
11/04/2010
Bushmills Ethanol, Atwater, MN 56209
natural gas leak
10/24/2009
Poet Refining, Caro, MI 48723
fire in the ductwork between the dryers and thermal oxydizer caught fire
10/13/10
Pinal Energy, 38585 W Cowtown Rd Maricopa, AZ 85139
explosion at a grain elevator
12/29/08
Glacial Lakes Energy
fire in large corn dryer
12/23/08
East Kansas Agri Energy
Ethanol Explosion
12/16/08
anildra Ethanol Plant, Bomaderry, NSW 2541
Australia
explosion
12/10/2008
Greater Ohio Ethanol, Lima OH
dust fueled fire in duct work
11/11/2008
Central Minnesota Ethanol Co-op, Little Falls, Minn.
explosion in a wood chip storage silo
10/29/08
Poet Biorefining Michigan Ethanol
fire in hot spots in the ductwork
9/23/08
Glacial Lakes Energy, Mina, SD 57451
electrical motor blamed for the fire at the bottom of a grain bin
8/30/08
Abengoa Bioenergy, York, NE 68467
fire in duct work
07/02/2008
Andersons Albion Ethanol, Sheridan Township, MI
explosion in the dryer
6/27/08
Poet Biorefining Mitchell, Loomis, S.D
flash fire,
01/03/2008
Pine Lake Corn Processors, Steamboat Rock, IA 50672
Dryer explosion
2007-dec
Central Minnesota Ethanol Co-op in Little Falls, Minn.
explosion in silo/biomass gasification system
10/27/07
AGP Ethanol plant, Hastings
fire in soybean meal dryer
7/29/06
Big River Resources, West Burlington, IA
fire in bin that is used to dry animal feed
9/21/05
Heartland Grain Fuels, Aberdeen, SD
dryer fire
11/14/04
Michigan Ethanol/Poet, Caro, MI
dryer fire during routine dryer shutdown
5/24/04
Great Plains Ethanol/Poet, SD
power outage/ fire stated when feed ignited
3/14/04
Gopher State Ethanol/ out of business
a piece of insulation fell into a heated area, setting the roof
on fire
7/26/03
Tri-County Ethanol/North Country Ethanol, S. Dakota
fire and explosion in the distillation area
12/31/02
Gopher State Ethanol, Saint Paul, MN
fire in grain drying unit
06/05/2002
Gopher State Ethanol, Saint Paul, MN
fire in grain drying unit
3/23/02
Corn Plus, Winebago, MN
older dryer fire
11/30/01
Heartland Grain Fuels, Aberdeen, SD
fire started after a valve allowed 200 proof raw alcohol to
drain onto the floor and run out an open door. A spark from welding equipment used by a crew working on the second floor of the building ignited the alcohol.
8/23/2000
New Energy, South Bend, Indiana
fire contained to the bag house. Spontaneous combustion the
cause
3/21/2000
Minnesota Energy, Buffalo Lake, MN
fire in the dryer
11/06/1998
Yokkaichi, Mie, Japan
explosion in recycle gas piping near reactor due to erosion
05/02/1997
Cornhusker Energy Lexington LLC, NE
natural gas rupture
12/24/2008
Manildra Park Petroleum, Australia

1/29/2004
Delta Oil Mill, Greenwood, Miss
grain fire
06/27/2011
Surat India
leak in ethanol pipeline
11/23/2003
Equistar Chemicals, Tuscola, Illinois
confined to a furnace
03/23/10
Agri-Energy, 1304 S. Main St., Garnett, Kansas

12/17/2008
Lincolnland Agri- Energy, Palestine, Ill
dryer
12/14/09
boiler or maintenance area explosion, caused severe damage at the plant
9-Jan-13
fire in a storage unit used to house grain and wheat at the FUEL Ethanol Plant in Pelham.
15-Sep-11
The fire was caused after a piece of burning conveyor belt fell into the bin.  Fire burns conveyor and 750,000 bushel grain.
4-Nov-10
explosion at an ethanol tank sent flames 40 feet in the air
24-Apr-09
Explosion and fire in a germ dryer and bagging processor. But the fire extended into the grain handling ductwork and spread to other pieces of equipment
19-Jan-09
The power at the facility went down.  The system that dries feed to make ethanol shut down, and heat inside the building caused some of the grain to start on fire.  The lack of power made it difficult to fight the fire.
14-Mar-04
the distillery at an Atchison alcohol plant exploded, throwing debris across Main Street and shaking surrounding buildings.
14-Sep-02



Train accidents do have the potential to do more than puncture a tank car. Ethanol train accidents, for example, have resulted in multiple car derailments that have sparked massive fireballs.  In one of the worst cases, in Cherry Valley, Illinois, in 2009, a derailment of 13 ethanol cars and resulting fire killed one person at a rail crossing and injured seven others, led to the evacuation of 600 homes, and caused $8 million in damages.

A number of large volume ethanol incidents have occurred. Some of these have resulted in significant fires, most of which have been allowed to burn. Water has been used in some incidents, primarily to protect nearby structures or tanks.  Alcohol-resistant foam has also been used, primarily to extinguish fires within tanker cars.  

Sampling and analysis of environmental media that has occurred in connection with spill response activities have shown impacts related to these spills, although they are generally of relatively short duration.  The most significant documented impact was a large fish kill that occurred in Kentucky as a result of a bourbon spill.  This effect was related to oxygen deficiency resulting from ethanol biodegradation, rather than direct toxicity. Another fish kill was observed subsequent to a spill in Illinois, but it has not been definitively attributed to the spill. 




Summary of Ethanol Incidents Nationwide between 2008 & 2014
Reviewed 40 incidents where ethanol or an unidentified hazardous material was released.
·         25 incidents involved release of ethanol
·         14 incidents involved release of unknown hazardous material
·         Four incidents had detailed reports available from the FRA or National Transportation Safety Board (NTSB).  Remaining information collected from media sources and crash reports.
·         Improper track inspections/maintenance and lack of communication were the major causes of the derailments.
·         Train speed and DOT-111 railcar design contributed to the release of ethanol.  One event resulted in a fatality, two events resulted in personal injury.
·         Average cost of damages to railroad property is $1,900,000 per incident.


Metropolitan Engineering, Consulting & Forensics (MECF)
Providing Competent, Expert and Objective Investigative Engineering and Consulting Services
P.O. Box 520
Tenafly, NJ 07670-0520
Tel.: (973) 897-8162
Fax: (973) 810-0440
We are happy to announce the launch of our twitter account. Please make sure to follow us at @MetropForensics or @metroforensics

Metropolitan appreciates your business.
Feel free to recommend our services to your friends and colleagues.